马小华研究员

发布时间:2021-02-28文章来源:材料科学与工程学院浏览:10

 

马小华,博士,男,湖北省荆州人,天津工业大学教授、博士生导师。

联系方式:电话:022-83955822;电子邮件:xhuama@tiangong.edu.cn

  

   

  

  

教育背景以及工作经历

2018.06 –天津工业大学,研究员,博导

2012.10 – 2018.6 Research Scientist R3,先进膜材料和孔材料研究中心,阿卜杜拉国王科技大学,沙特阿拉伯。导师:Ingo Pinnau.

2009.10 - 2012.10博士后,先进膜材料和孔材料研究中心,阿卜杜拉国王科技大学,沙特阿拉伯。导师:韩宇,Ingo Pinnau.

2004.7 - 2009.7博士,聚合物科学与工程系,北京大学。导师:宋乃恒,周其凤。

2000.9 - 2004.7学士,高分子材料与工程系,四川大学。导师:顾宜。

研究兴趣

1:可溶,新型,微孔聚酰亚胺功能膜材料在气体的存储和分离方面的应用。(包括天然气提纯,氧气/氮气的分离,以及氢气/氮气的分离等)。

2:高性能聚酰亚胺膜材料的合成与制备。

3:有机多孔晶体材料 (COF, HOF, etc)的合成与应用。

讲授课程:为留学生开设《Polymer Chemistry》课程。

在研课题

  1. 2021.01-2024.12,国家自然科学基金面上项目,高性能富氦聚合物分子筛膜的分子设计与分离机制,64万。项目负责人。

  2. 2020.12-2021.12.低温膜法空分技术可行性研究,横向,8万。项目负责人

  3. 2019.04-2021.04.天津市科技计划项目,可溶性聚合物分子筛膜材料的分子设计以及在氧气氮气分离中的研究,200万项目负责人。

  4. 2018.01-2020.12.国家自然科学基金青年项目“交联型内孔聚酰亚胺的分子设计以及气体分离性质研究”项目负责人,25万。编号:51703036。项目负责人。项目负责人(已经结题)。

  5. 2018.06 -2020.09.天津市青年千人启动基金:100万。项目负责人。

  6. 2019.01-2020.12.新型微孔,交联网络型聚酰亚胺膜材料在CO2/CH4分离方面的探索,10万,山西煤化所开放基金,项目负责人(已经结题)。

  7. 2017.12 -2019.7.新型内孔聚合物氧气/氮气分离膜的分子设计与性能研究,膜国家重点实验室开放课题,10万, 项目负责人(已经结题)。

发表文章(仅列出通讯作者以及第一作者的文章)

  1. Zhiyang Zhu,Hao Dong,Kaihua Li, Qixuan Li, Jianxin Li*,Xiaohua Ma*. One-step synthesis of hydroxyl-functionalized fully carbon main chain PIMs via a Friedel-Crafts reaction for efficient gas separation.Sep Purif Technol2021,262:118313.

  2. Wenhui Ji, Kaihua Li, Yong-Gang Min,Wenxiong Shi,* Jianxin Li,*Xiaohua Ma*Remarkably Enhanced Gas Separation Properties of PIM-1 at Sub-Ambient Temperatures, Journal of membrane science, 2021,623, 119091.

  3. Zhiyang Zhu, Wenxiong Shi, Wenhui Ji, Jianxin Li,*Yingge Wang, Ingo Pinnau*,Xiaohua Ma*Unprecedented gas separation performance of a difluoro- functionalized triptycene-based ladder PIM membrane at low temperature, 2021,doi.org/10.1039/D0TA09703A.(Back cover)

  4. Zhiyang Zhu,Junjie Zhu, Jianxin Li,Xiaohua Ma*Enhanced Gas Separation Properties of Tröger’s Base Polymer Membranes Derived from Pure Triptycene Diamine Regioisomers.Macromolecules2020,53, 1573-1584.

  5. Quanji Zhu,Xiaohua Ma *, Hongchang Pei, Jiaye Li, Feng Yan, Zengyu Cui, Hong Wang, Jianxin Li*. A highly-efficient lithium adsorptive separation membrane derived from a polyimide-containing dibenzo-14-crown-4 moiety. Sep Purif Technol 2020,247:116940.

  6. Xiaohua Ma, Holden Lai, Yingye Wang, A Alhazmi, Yan Xia, Ingo Pinnau*. Facile Synthesis and Study of Microporous Catalytic Arene-Norbornene Annulation–Tröger’s Base Ladder Polymers for Membrane Air Separation. ACS Macro Letters 2020,9(5):680-685.

  7.  ShaoLu Li, Zhiyang Zhu, Jianxin Li*, Yunxia Hu*,Xiaohua Ma *. Synthesis and gas separation properties of OH-functionalized Tröger's base-based PIMs derived from 1,1′-binaphthalene-2,2′-OH.Polymer2020,193:122369.

  8. Yingnan Ma, Zhaopeng Dong, Meng You, Yufeng Zhang, Xianshe Feng,Xiaohua Ma*. Jianqiang Meng*, Formation of a thin and continuous MOF membrane with 2-D MOF nanosheets as seeds via layer-by-layer growth,Chem Commun, 2019, 55, 10146-10149.

  9. Xiaohua Ma, Yingge Wang, Kexin Yao, Zain Ali, Yu Han and Ingo Pinnau,Pristine and Carboxyl-Functionalized Tetraphenylethylene-Based Ladder Networks for Gas Separation and Volatile Organic Vapor Adsorption,ACS Omega, 2018,3, 15966–15974.

  10. Xiaohua Ma, Ramy Swaidan, Yingge Wang, Chia-en Hsiung, Yu Han and Ingo Pinnau. Highly Compatible Hydroxyl-Functionalized Microporous Polyimide-ZIF-8 Mixed Matrix Membranes for Energy Efficient Propylene/Propane Separation.ACS Appl. Nano Mater.,2108, 1,3541–3547.

  11. 11:Xiaohua Maand Ingo Pinnau, “Effect of Film Thickness and Physical Aging on “Intrinsic” Gas Permeation Properties of Microporous Ethanoanthracene-Based Polyimides”.Macromolecules. 2018,51, 1069–1076.

  12. Xiaohua Ma,Mahmoud Abdulhamid, Xiaohe Miao and Ingo Pinnau, “Facile Synthesis of a Hydroxyl-Functionalized Tröger’s Base Diamine: A New Building Block for High-Performance Polyimide Gas Separation Membranes”.Macromolecules, 2017,50, 9569-9576.

  13. Xiaohua Ma, Mahmoud A. Abdulhamid, Ingo Pinnau,Design and Synthesis of Polyimides Based on Carbocyclic Pseudo-Tröger’s Base-Derived Dianhydrides for Membrane Gas Separation Applications”.Macromolecules, 2017,50, 5850–5857.

  14. 14:Xiaohua Ma, Mohsin Mukaddam, Eric Litwiller, Ingo Pinnau.Bifunctionalized Intrinsically Microporous Polyimides with Simultaneously Enhanced Gas Permeability and Selectivity.Macro. Rapid Commu.,2016, 37, 900-904 (Front Cover).

  15. 15:Xiaohua Ma, Ingo Pinnau.A Novel Intrinsically Microporous Ladder Polymer and Copolymers Derived from 1,1′,2,2′-tetrahydroxy-tetraphenylethylene for Membrane-based Gas Separation.Poly. Chem., 2016,7, 1244-1248 (Front Cover)

  16. Xiaohua Ma, Bader Ghanem, Octavio Salines, Eric Litwiller, Ingo Pinnau.Synthesis and Effect of Physical Aging on Gas Transport Properties of a Microporous Polyimide Derived from a Novel Spirobifluorene-Based Dianhydride.Acs Macro Lett., 2015,4, 231-235.

  17. Xiaohua Ma,Octavio Salines, Eric Litwiller, Ingo Pinnau.Pristine and Thermally-rearranged Gas Separation Membranes from Novel o-Hydroxyl-Functionalized Spirobifluorene-based Polyimides.Poly. Chem.,2014,5, 6914-6922. (Front Cover)

  18. Xiaohua Ma, Octavio Salines, Eric Litwiller and Ingo Pinnau.Novel Spirobifluorene- and Dibromospirobifluorene-Based Polyimides of Intrinsic Microporosity for Gas Separation Applications.Macromolecules, 2013,46, 9618-9624.

  19. Xiaohua Ma, Raja Swaidan, Baiyang Teng, Hua Tan, Octavio Salines, Eric Litwiller, Ingo Pinnau, and Yu Han.Carbon Molecular Sieve Gas Separation Membranes Based on Intrinsic Microporous Polyimide Precursor.Carbon, 2013, 62, 88-96.

  20. Xiaohua Ma, Raja Swaidan, Youssef Belmabkhout, Yihan Zhu, Eric Litwiller, Mustapha Jouiad, Ingo Pinnau, and Yu Han.Synthesis and Gas Transport Properties of Hydroxyl-Functionalized Polyimides with Intrinsic Microporosity.Macromolecules, 2012, 45, 3841-3849.

  21. Xiao-Hua Ma, Li-Min Fu, Yunfeng Zhao, Xi-Cheng Ai, Jian-Ping Zhang, Yu Han and Zhi-Xin Guo.Chiral Crystal of a C2v-Symmetric 1,3-Diazaaulene Derivative Showing Efficient Optical Second Harmonic Generation.J. Polym. Sci. Part. B, Poly. Phys., 2011,49, 649-656.

  22. Xiaohua Ma,Fei Ma, Zhenhua Zhao, Naiheng Song and Jianping Zhang.Toward Highly Efficient NLO Chromophores: Synthesis and Properties of Heterocycle-Based Electronically Gradient Dipolar NLO Chromophores.J. Mater. Chem.,2010,20, 2369-2380.

  23. Xiaohua Ma, Fei Ma, Zhenhua Zhao, Naiheng Song and Jianping Zhang.Synthesis and Properties of NLO Chromophores with Fine-Tuned Gradient Electronic Structures.J. Mater. Chem., 2009,19, 2975-2985.

  24. Xiaohua Ma,Ran Liang, Fan Yang, Zhenhua Zhao, Aixin Zhang, Naiheng Song, Qifeng Zhou and Jianping Zhang.Synthesis and Properties of Novel Second-Order (NLO) Chromophores Containing Pyrrole as An Auxiliary Electron Donor.J. Mater. Chem.,2008,18, 1756-1764.

专利

  

  1. Xiaohua Ma, Ingo Pinnau, Bader Ghanem, “Dianhydrides, Polyimides, Methods of Making Each, and Method of Use”,PCT,2013, Pub No, WO2015001422A2.

  2. Xiaohua Ma, Bader Ghanem, Ingo Pinnau, “O-hydroxyl-functionalized Diamines, Polyimides, Method of Making Each, and Method of Use”,PCT,2014,. WO2016009273A3.

  3. Xiaohua MaDianhydrides, Polyimides derived from biscatecol, methods of making, and method of use”, US,2015, US20180371168A1

  4. Xiaohua Ma, Ingo Pinnau,Troger's base-based monomers, and polymers, methods of making and uses thereof,PCT,2016,WO2017221135A1.

  5. 马小华,李凯华,朱芷杨,一种气体透过率的恒体积变压法测试系统,中国专利,CN111266015 A

编撰书籍:

Xiao-Hua Ma, Shi-Yong Yang, Advanced Polyimide Materials, Synthesis, Characterization, and Applications, chapter 6,Polyimide Gas Separation Membranes, Elsevier,2018, 257–322.