李振环教授

发布时间:2017-01-18文章来源:材料科学与工程学院浏览:1335


李振环(19753月),博士、教授、博士生导师。

1简介

2006年获得中国科学院理学博士学位2009被聘为天津市科技

特派员2012获得天津市高校中青年骨干创新人才2013年获得天津市131第一层次人才”,2016年获得天津市“131创新型人才团队”资助。近年来申请人主持科研基金16项,发表论文80余篇,其中SCIEI论文60篇,申请专利20项,承担J. Hazard. Mater.Scientific ReportsRSC AdvFuel Process.Technol.Appl. Catal. A.等近20种期刊论文审稿。开发了非氯化锂体系合成高性能聚苯硫醚(PPS)技术,并在天津石化完成了百吨级中试;联合开发了“半连续化”千吨PPS产业化工艺包,在天津石化进行“半连续化”示范生产线建设。开展了PPS改性和成形研究,实现了PPS熔喷过滤材料、气液过滤用PPS膜材和PPS纤维材料(含鬃丝)的中试生产等。在山东易澳科技有限公司完成了“优级碳酸二丁酯产品”千吨规模工业化生产(纯度99.5%以上);开发了生物质为原料规模化合成呋喃二甲酸和全生物基呋喃聚酯技术(包含工艺和设备-);开发碳酸二甲酯酯交换法制备了高性能芳香族和脂肪族聚碳酸酯技术,研究了反应规律,解析了聚酯结构与性能的关系(阻隔氧效率、防紫外辐射和透光等性能的内在关系)。参与组建了“天津市聚酯新材料技术工程中心”和“聚芳类高分子材料循环产业链战略联盟”,并担任“山西省科技创新项目”首席专家。

2、联系方式

Email: Zhenhuanli1975@aliyun.com, Lizhenhuan@tjpu.edu.cnZhenhuanli@sohu.com;手机15900336043、座机022-83955358;联系地址:天津市西青区宾水西道399号、材料科学与工程学院;邮编 300387

3、研究方向

1耐高温和抗腐蚀性过滤材料合成、改性、成形及其气液过滤性能研究:高性能聚苯硫醚基材料合成改性聚苯硫醚成膜技术和熔喷技术开发,极端环境用膜材料和膜过程,碳基材料改性特种纤维和树脂研究(聚醚酮酮、聚酰亚胺和芳纶等材料合成与应用)。

2资源环境的综合利用技术:生物质法合成5-羟甲基糠醛、呋喃二甲酸和呋喃基聚酯,以及全生物基聚酯在过滤材料和膜材料中的应用;CO2固定合成精细化学品和聚合物技术;氨基酸的可控聚合及蛋白或多肽的性能研究酶和蛋白等催化生物质转化研究

3非光气法合成碳酸酯、聚碳酸酯和氨基酸酯技术,聚碳酸酯开发和应用研究。

4新型有机和无机多孔催化材料制备及其在能源和精细化学品制备中的应用。

4、主持和完成项目

在研项目:

1DMC法合成α-氨基酸-N-羧酸酐及其定向酰基化和靶向关环催化机制研究国家自然科学基金(2167620264万)201701月至 202012,主持;

2ArnSnOm靶向催化二甲氧基碳酸双份A二酯合成、缩合及反应机理研究,国家自然基金(2137617780万)、2013-01-2017-12、主持;

3)工程塑料用聚苯硫醚产品的研究开发(21609080万),2016.01-2017.12

4聚苯硫醚技术研究及产品开发(立项:200/1720万),2017.01-2020.12,主持;

5)中空纤维膜用PPS基树脂制备、膜结构调控极其应用研究,天津市自然科学基金重点项目(15JCZDJC3700020)201504-2018.03,主持;

6超纯碳酸二丁酯合成技术、山东禹城易澳科技有限公司(180万)、2014/03 -2015/12、主持;

7)中空纤维膜用聚苯硫醚基树脂制备、结构调控及其膜应用研究,中国纺织工业联合会应用基础研究(J201406: 20万),2015.1-2017.12、主持;

8)纤维过滤材料(120万):天津市131创新团队(2017.01-2020.12)、负责人。

  

完成项目:

1) 聚苯硫醚中空纤维微纳虑膜及膜反应器的规模化制备技术(201401002: 300),山西省科技创新项目,2014.1-2016.12、主持,已鉴定

2聚苯硫醚合成工艺优化和工艺包编制、中石化(2011100100/940)、2011-01- 2014-12、主持,已验收

3聚苯硫醚聚合机理和聚合过程调控技术研究(21503880万)2015.01-2016-12,主持,已验收;

4)天津市高校中青年骨干创新人才培养计划2013/01-2015/12、主持,已验收

5杂化石墨烯催化纤维素一锅法绿色转化制备5-HMF、天津市自然基金重点项目(12JCZDJC2980020万)、2012-04-2015-03、主持,结题;

6)结构单元厚度的MFI片层上复合杂化有机氧化锡的催化剂制备及其强化DmC(1)合成的研究(2100607119万)、国家自然基金、2011.1-2013.12、主持,结题

7碳酸二甲酯绿色可控合成双酚A型聚碳酸酯的研究、天津市自然基金(09JCYBJC0300010万)、2009-04-2012-03、主持,结题

8)聚苯硫醚树脂合成以及应用技术开发、中石化(2008068160/405)、2008-01- 2011-12、主持,已验收

9Spherizone工艺PP树脂结构表征与评价、中石化(天津分公司:10万)、2009-01-2011-12、主持,完成

10)离子液体调控聚碳酸酯的合成及聚酯性能考察,天津市高等学校基金(20070672万)、2007-03-2010-04、主持,结题

11)烧结形成致密陶瓷结构阻燃电缆的合成及性能测试、天津市高等学校基金(特派员:3万)、2009-01-2010-12、主持,结题

12)闪蒸纺制备聚苯硫醚无纺布极其性能研究、纺织协会(40万)、2009-01- 2012-12、主持,完成

13)油墨用酚醛树脂的合成研究、阿莱斯国际有限公司(30万)、2008-01- 2011-12、主持,完成

14)聚苯硫醚树脂性能与分析、天津石化(3.35万)、2011-01-2012-12、主持,完成

15碳酸酸酯类化合物的绿色合成研究、天津科汇达有限公司项目(20万)、2008/10- 2009/09、主持,结题

16)两个不同谱系DEF/AP3亚家族基因在花发育过程中调控机制研究、国家自然基金(3090009219万)、结题、2010.01-2012.12、第一参与;

17)磺胺类药物的合成与改性研究,山东鲁抗药品经营有限公司(12万),2008.3-2010.3、第一参与,结题

18)新型阻燃腈纶纤维的开发及应用研究、中石化(80万)、2007-01- 209-12、参与,结题


5、论文

1. Lei Cao, Zhenhuan Li*, Yu Gu, Daohao Li, Kunmei Su, Dongjiang Yang*,Bowen Cheng*, Rational Design ofFe/Fe2N/Fe3C@N-doped Carbon Nanobox as Efficient Oxygen Reduction Catalyst for Zn-air Batteries, Journal of Materials Chemistry A,2017, 接收SCI收录, 影响因子8.3,一区

2. Maliang Zhang, Xiaotian Wang, Bowen Cheng*, Zhenhuan Li*,C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property, Scientific Reports, 2017接收SCI收录,影响因子5.3, 二区)

3. Yali Bai, Zhenhuan Li, * Bowen Cheng, Maliang Zhang and Kunmei Su,Higher UV-shielding ability and lowerphotocatalytic activity of TiO2@SiO2/APTES and itsexcellent performance in enhancing thephotostability of poly(p-phenylene sulfide), RSC Adv., 2017, 7, 21758SCI收录,影响因子3.84, 二区.

4. Xiaotian Wang, Zhenhuan Li,* Maliang Zhang, Tingting Fan and Bowen Cheng*, Preparation of a polyphenylene sulfide membranefrom a ternary polymer/solvent/non-solventsystem by thermally induced phase separation, RSC Adv., 2017, 7, 10503SCI收录,影响因子3.84, 二区.

5. Xing-hai Zhou, Jing-ge Ju, Zhen-huan Li, Ma-liangZhang, Nan-ping Deng, Bo-wen Cheng, Wei-minKang, Design and fabrication of flexible mesoporous SidopedAl2O3 ultrafine fibers by electro-blowspinning (EBS) technique, Ceramics International, DOI: http://dx.doi.org/10.1016/j.ceramint.2017.04.148,SCI收录,影响因子2.8, 二区.

6. Xing-hai Zhou, Lei L, Zhen-huan Li*, Lan-lan Fan, Wei-min Kang, Bo-wen Cheng, The preparation of continuous CeO2/CuO/Al2O3 ultrafine fibers by Electro-blowing spinningEBSand its photocatalytic activity, Journal of Materials Science: Materials in Electronics, 2017, 接收SCI收录,影响因子1.79, 三区

7. Qinghua Wang, Kunmei Su*, Zhenhuan Li* and Bowen ChengPerformance of [Emim]Br, [Bmim]Br and 2,5-furandicarboxylic acid in fructose conversion to 5-hydroxymethyfurfuralJ. Mol. Catal. A:Chem. 2017,接收(SCI收录,影响因子4.0, 二区).

8. Tingting Fan, Zhenhuan Li*,Bowen Cheng*, Preparation of PPS membrane with Berberis thunbergii var.atropurpurea Chenault leaf like structure and its excellent performance in vacuum membrane distillation, J.membrane Science 2017, 修改(SCI收录,影响因子5.5, 一区).

9. Yuan Gao, Zhenhuan Li, Kunmei Su, Bowen Cheng, Excellent performance of TiO2(B) nanotubes in selectivetransesterification of DMC with phenol derivativesChemical Engineering Journal 301 (2016) 12–18SCI收录,影响因子5.3,一区.

10.Li Shuang, Su Kunmei*, Li Zhenhuan*, Cheng Bowen, Selective oxidation of 5-hydroxymethylfurfural with H2O2 catalyzed by a molybdenum complex, Green Chemistry, 2016, Green Chem., 2016, 18, 2122–2128SCI收录,影响因子8.6, 一区.

11.Wang Xuyan, Su Kunmei, Li Zhenhuan*, Cheng Bowen*,  The larger area graphene formation from the small GO sheet in presence of basic divalent sulfide species and its usage in biomass conversion, RSC Adv., 2016, 6, 11176–11184SCI收录,影响因子3.84, 二区.

12. Lechen Diao, Kunmei Su,* Zhenhuan Li* and Changkun Ding, Furan-based co-polyesters with enhanced thermalproperties: poly(1,4-butylene-co-1,4-cyclohexanedimethylene-2,5-furandicarboxylicacid), RSC Adv., 2016, 6, 27632–27639SCI收录,影响因子3.84, 二区.

13. Chenyang Li, Zhenhuan Li,* Lei Cao, and Bowen Cheng*, Graphene Preparation by Phenylmagnesium Bromide and ItsExcellent Electrical Conductivity Performance in Graphene/Poly(pphenylenesulfide) Composites, Ind. Eng. Chem. Res. 2016, 55, 10860−10867SCI收录,影响因子2.6, 二区.

14. Maliang Zhang, Xiaotian Wang, Chenyang Li, Yali Bai, Bowen Cheng*and Zhenhuan Li*, Effects of hydrogen bonding between MWCNT andPPS on the properties of PPS/MWCNT composites, RSC Adv., 2016, 6, 92378–92386SCI收录,影响因子3.84, 二区.

15. Lei Cao, Zhenhuan Li, Kunmei Su & Bowen Cheng, Hydrophilic Graphene Preparationfrom Gallic Acid Modified GrapheneOxide in Magnesium Self-Propagating High TemperatureSynthesis Process, Scientific Reports | 6:35184 | DOI: 10.1038/srep35184.SCI收录,影响因子5.3, 二区.

16. Huanfeng Jiao, Xiaoliang Zhao, Chunxiao Lv, Yijun Wang, Dongjiang Yang, Zhenhuan Li, Xiangdong Yao, Nb2O5-γ-Al2O3 nanofibers asheterogeneous catalysts forefficient conversion of glucose to5-hydroxymethylfurfural, Scientific Reports, 6:34068, DOI: 10.1038/srep34068.SCI收录,影响因子5.3, 二区.

17. Zhang Maliang, Su Kunmei*, Song Huanmeng, Li Zhenhuan*, Cheng Bowen, The excellent performance of amorphous Cr2O3, SnO2, SrO and graphene oxide–ferric oxide in glucose conversion into 5-HMF, Catal. Commun., 2015, 5, 76-80.).SCI收录,影响因子3.84, 三区.

18. Zhang Maliang, Wang Haixia, Li Zhenhuan* and Bowen Cheng*, Exfoliated graphite as a filler to improve poly(phenylene sulfide) electrical conductivity and mechanical properties, RSC Adv., 2015,5, 13840-13849.SCI收录,影响因子384, 二区

19. Xia Ranran, Li Zhenhuan*, Cheng Bowen*, Su Kunmei, The structure of organotin oxides playing a key role on the transesterfication of dimethyl carbonate with hydrogenated bisphenol A. Korean J. Chem. Eng., 2014, 31(3):427-430. SCI收录, 影响因子1.6, 三区

20. Ma Yinggai, Li Zhenhuan*, Su kunmei, Cheng Bowen. Autocatalytic esterification of glutamic acid by Benzyl Alcohol with CuCl2 promoting. Catal.Commun. 2014, 48: 15-18. SCIEI收录, 影响因子3.3, 三区

21. Kunmei Su, Xin Liu, Min Ding, Zhenhuan Li*, Bowen Cheng*, Effective conversion sucrose into 5-hydroxymethylfurfural by tyrosine in [Emim]Br, J. Mol. Catal.A 2013,379 (15)350-354SCIEI收录, 影响因子4.0, 二区

22. He Xiaolong, Zhenhuan Li*, Kunmei Su, Bowen Cheng, Jun Ming, Study on the reaction between bisphenol A and dimethyl carbonate over organotin oxide, Catal. Commun. 2013, 33, 20-23. SCIEI收录, 影响因子3.3, 三区

23. Li Zhenhuan*, Su Kunmei, Cheng Bowen, Ming Jun, Zhang Lei, Xu Yongchao, Promotion of organotin modified SBA-15 inthe selective carboxylation of BPA with DMC, Catal. Commun.,2011, 12:932-935. SCIEI收录, 影响因子3.3, 三区

24. Su Kunmei, Li zhenhuan*, Cheng Bowen, Zhang Lei, Zhang Maliang, Ming Jun, The studies on the Friedel-Crafts acylation of toluene with acetic anhydride over PW/TiO2, Fuel Process. Technol., 2011, 92:2011-2015. SCIEI收录, 影响因子3.9, 二区

25. Kunmei Su, Zhenhuan Li*, Bowen Cheng*, Kun liao, Dexin Shena, Yufei Wang, Studies on the carboxymethylation and methylation of bisphenol A with dimethyl carbonate over TiO2/SBA-15, J. Mol. Catal. A: Chem., 2010, 315:60-68. SCIEI收录, 影响因子4.0, 二区

26. Zhenhuan Li*, Kunmei Su, Bowen Cheng*, Yanchao Deng, Organically modified MCM-type material preparation and its usage in controlled amoxicillin delivery, J. Colloid Interface Sci. J. Colloid Interface Sci. 2010, 342: 607-613. SCI收录, 影响因子3.9TOP论文, 二区

27. Zhenhuan Li*, Kunmei Su, Bowen Cheng, Effects of VOx/AlMCM-41 surface structure on ethylbenzene oxydehydrogenation in the presence of CO2,Catal. Lett, 2010, 135: 135–140.SCI收录, 影响因子2.25, 三区

28. Kunmei Su, Zhenhuan Li*, Bowen Cheng, Yuanlin Ren, Lingli Yu, Fan Wang, Catalytic performance of metal oxide modified MCM-41 catalyst in Diphenyl carbonate synthesis, Kinetics and Catalysis, 2010, 51(3): 359–363. SCI收录, 影响因子1.0, 四区

29. Zhenhuan Li*,Bowen Cheng, Kunmei Su, Debenzylation of benzyl phenyl ether and its derivatives with acetic anhydride over zeolite,Catal. Commun. 2009, 10: 518-521. (SCIEI收录, 影响因子3.8, 三区

30. Zhenhuan Li*, Bowen Cheng, Kunmei Su, Yu Gu, Yuanlin Ren, Peng Xi, The Synthesis of Diphenyl Carbonate from Dimethyl Carbonate and Phenol over Mesoporous MoO3/SiMCM-41, J. Mol. Catal. A: Chem. 2008, 289: 100-105. SCIEI收录, 影响因子4.0, 二区

31. Kunmei Su, Zhenhuan Li*, Bowen Cheng, Yuanlin Ren, The decomposition of CCl4 into Diphenyl Carbonate over MClχ/SiMCM-41, Catal. Commun. 2008, 9: 1666- 1670. (SCIEI收录, 影响因子3.3,三

32. Li, Zhenhuan; Cheng, Bowen; Kunmei, Su, Piperidinium 3-carboxy-4-hydroxy- benzenesulfonate monohydrate,  ACTA CRYSTALLOGRAPHICA, 2008, 64, O1085 -U2240. SCI收录, 四区.

33. Zhenhuan Li*, Kunmei Su, The direct reaction between CO2 and phenol catalyzed by bifunctional catalyst ZrO2,J. Mol. Catal. A: Chem. 2007, 277: 180–184. SCIEI收录, 影响因子4.0, 二区

34. Zhenhuan Li*, Zhangfeng Qin, Synthesis diphenyl carbonate from Phenoxide and carbon dioxide in carbon tetrachloride with zinc halide as catalyst, J. Mol. Catal. A: Chem. 2007, 264: 255–259. SCIEI收录, 影响因子4.0, 二区

35. Zhenhuan Li*, Zhangfeng Qin, Huaqing Zhu, Jianguo Wang. Synthesis of diphenyl carbonate from CO2, phenoxide, and CCl4 with ZnCl2 as catalyst, Chem. Lett. 2006, (7): 784~785. SCI收录, 影响因子1.6, 四区

36. Su kunmei, Li Zhenhuan, Chen Zhiduan, CsPI from the perianthless early- diverging Chloranthus spicatus show function on petal development in Arabidopsis thaliana, Botanical Studies, 2014. DOI: 10.1186/1999-3110-55-21 .SCI收录, 影响因子1.4, 四区

37. Bin Deshan, Wang Hong, Li Jianxin, Wang Hui, Yin Zhen, Kang Jianli, He Benqiao, Zhenhuan Li., Controllable oxidation of glucose to gluconic acid and glucaric acidusing an electrocatalytic reactor, Electrochimica Acta 130 (2014) 170–178. SCI收录, 影响因子4.8, 二区